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Re: IIT Chemistry Syllabus
Here I am providing the syllabus of IIT Madres Chemistry. Chemistry syllabus: Transition Metal Chemistry Structure, bonding and properties of transition metal ligand complexes – ligand, coordination, geometry, coordination number, isomerism (recapitulation); HSAB concept, thermodynamic stability, successive and overall stability constants, Irving-William series, chelate and macrocyclic effect. Theories of bonding - VBT, CFT and their limitations; d-orbital splitting in octahedral, JT-distorted octahedral, square planar, square pyramidal, trigonal bipyramidal, and tetrahedral complexes; CFSE for d1 to d10 systems, pairing energy, low-spin and high-spin complexes and magnetic properties; LFT, and molecular orbital (MO) theory of selected octahedral and tetrahedral complexes. Electronic Spectra - UV-Vis, charge transfer, colors, intensities and origin of spectra, interpretation, term symbols and splitting of terms in free atoms, selection rules for electronic transitions, Orgel and Tanabe-Sugano diagram, calculation of Dq, B, C, Nephelauxetic ratio. Reaction mechanisms - substitution reactions in octahedral and square planar complexes, Tran’s effect and its influence, water exchange, anation and base hydrolysis, stereochemistry, inner and outer sphere electron transfer mechanism. Lanthanides and Actinides - contraction, coordination, optical spectra and magnetic properties. Organometallic Chemistry Valence electron count (16/18 electron rules); structure and bonding in mono and polynuclear metal carbonyls; substituted metal carbonyls and related compounds; synthesis and reactivity of metal carbonyls; vibrational spectra of metal carbonyls; dinitrogen and dioxygen as ligands in organometallic compounds. Types of M-C bonds; synthesis and reactivity of metal alkyls, carbenes, alkenes, alkynes, and arene complexes; metallocenes and bent metallocenes; isolobal analogy Reactions of organometallic complexes: Substitution, oxidative addition, reductive elimination, insertion and deinsertion; Catalysis - Hydrogenation, Hydroformylation, Monsanto process, Wacker process, alkene polymerization. Rest of detailed syllabus, here I am providing a link, from where you can get the IIT Madras chemistry syllabus. The link is: chem.iitm.ac.in/syllabus.html |
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