Saurashtra University B.Sc Chemistry Syllabus

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Saurashtra University B.Sc Chemistry syllabus

Semester-I

C-101: Chemistry Theory

3 Credits

100 Marks

Unit– I: Inorganic Chemistry

1. Atomic structure and periodic properties[10 Hours]
Dual nature of electron, De-Broglie’s equation, Heisenberg’s uncertainty principle,
quantum numbers, Aufbauprinciple, Pauli’s exclusion and Hund’s rule for electron
configuration.
Periodicity in atomic properties and its causes, explanation of general trends of
periodic properties: atomic and ionic radii, ionization potential, electronegativity and
electron affinity.
Chemistry of s and p block elements
Special characteristics such asmetallic character, polarizing power, hydration
energy,inert pair effect, relative stability of different oxidation state, diagonal
relationship of (1) lithium with magnesium (2) boron with silicon and (3) beryllium
with aluminum, anomalous behavior of Li and Be, formation of complex compounds,
catenation, allotropy (diamond and graphite-theirstructure, properties and its uses).
2. Chemical bonding in covalent compounds [10 Hours]
Covalent bond: Valence bond theory and its limitations. Concept of hybridization:
sp(BeCl2), sp2 (BF3), sp3 (SiH4), sp3d (PCl5) and sp3d2 (SF6).
Stereochemistry of inorganic molecules: Sidgwick Powell rule and VSEPR theory.
Structure of molecules: SnCl2, SO4
-2, CO3
-2.
Basic concept of MO theory.Bonding and anti-bonding molecular orbitals.Gerade
and ungerade molecular orbitals.σ-molecular orbital andσ*-molecular orbital, π-
molecular orbital and π*-molecular orbital.Conditions for effective combinations of
atomic orbitals.Energy level diagrams of B2, C2, N2, O2, F2, CO, NO, CO2 (with s-p
mixing and orbital interaction) with calculation of bond order and magnetic
moment.Comparison of MO theory and VB theory.

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Saurashtra University Rajkot
Saurashtra University Campus, Rajkot, Gujarat 360005