MLSU M Sc Chemistry Syllabus

Can you provide me the syllabus of Chemistry (Previous/Final) 2010-2011 as offered by MLSU or Mohanlal Sukhadia University Udaipur Rajasthan?

[shikha]

The syllabus of Chemistry (Previous/Final) 2010-2011 as offered by MLSU or Mohanlal Sukhadia University Udaipur Rajasthan is as follows:

PAPER-I
INORGANIC CHEMISTRY

UNIT-I
Metal ligand bonding - Limitations of CFT, Ligand
field theory, MOT-octahedral, tetrahedral and square
planar complexes, MO theory & π-bonding, correlation
(Walsh diagrams) dπ - pπ bonding.
Electronic spectra of transition metal complexesSpectroscopic
ground states, Orgel and Tanabe -
Sugano diagram (d1 to d9 states), calculation of Dq, B
and b parameters, charge transfer spectra

UNIT-II
Metal π- complexes - I – Carbonyls, structure and
bonding, use of vibrational spectra of metal carbonyls
for bonding and structure elucidation, types of
carbonyls, their preparations and important reactions.

UNIT-III
Metal π- complexes - II - Preparation, bonding,
structure and important reactions of transition metal
nitrosyls, dinitrogen and dioxygen complexes.

UNIT-IV
Boranes - Preparation and important reactions,
electron deficient characters of boranes, structure
and bonding in boranes, concept of multicentric
bonding and M.O description, Lipscomb concept of
bonding elements, semitopological description of s, t,
y and x nomenclature.
Silicones - Preparation, properties and structure of
silicones , their industrial and technical importance.

UNIT-V
Sulphur-Nitrogen compounds - Preparation, properties
of tetrasulphur tetranitride, disulphur dinitride,
polythiozyl and other sulphonitrides, sulphur imides.
Phosphorus- Nitrogen compounds - Linear and cyclic
polymers, their synthesis and reactions, structure
and bonding, Allock’s skeletal π—bonding concept