28th September 2012 06:07 PM | |
Saksham | Re: IIT Jam Chemistry Books Here I am giving you syllabus of the IIT JAM Chemistry. CHEMISTRY (CY) PHYSICAL CHEMISTRY Basic Mathematical Concepts: Functions, maxima and minima, integrals, ordinary differential equations, vectors and matrices, determinants, elementary statistics and probability theory. Atomic and Molecular Structure: Fundamental particles, Bohr's theory of hydrogen-like atom; wave-particle duality; Uncertainty principle; Schrodinger's wave equation; Quantum numbers, shapes of orbitals; Hund's rule and Pauli's exclusion principle, electronic configuration of simple homonuclear diatomic molecules. Theory of Gases: Equation of state of ideal and nonideal (van der Waals) gases, Kinetic theory of gases. Maxwell-Boltzmann distribution law; equipartition of energy. Solid state: Crystals, crystal systems, X-rays, NaCl and Kcl structures, close packing, atomic and ionic radii, radius ratio rules, lattice energy, Born-Haber cycle, isomorphism, heat capacity of solids. Chemical Thermodynamics: Reversible and irreversible processes; First law and its application to ideal and nonideal gases; Thermochemistry; Second law; Entropy and free energy, Criteria for spontaneity. Chemical and Phase Equilibria: Law of mass action; Kp, Kc, Kx and Kn; Effect of temperature on K; Ionic equilibria in solutions; pH and buffer solutions; Hydrolysis; Solubility product; Phase equilibria-Phase rule and its application to one-component and two-component systems; Colligative properties. Electrochemistry: Conductance and its applications; Transport number; Galvanic cells; EMF and Free energy; Concentration cells with and without transport; Polarography; Concentration cells with and without transport; Debey-Huckel-Onsagar theory of strong electrolytes. Chemical Kinetics: Reactions of various order, Arrhenius equation, Collision theory; Theory of absolute reaction rate; Chain reactions - Normal and branched chain reactions; Enzyme kinetics; photochemical processes; Catalysis. Adsorption: Gibbs adsorption equation, adsorption isotherm, types of adsorption, surface area of adsorbents, surface films on liquids. ORGANIC CHEMISTRY Basic Concepts in Organic Chemistry and Stereochemistry: Electronic effect (resonance, inductive, hyperconjugation) and steric effects and its applications (acid/base property). Optical isomerism in compounds without any stereocenters (allenes, biphenyls), conformation of acyclic systems (substituted ethane/n-propane/n-butane) and cyclic systems (mono and di substituted cyclohexanes). Organic Reaction Mechanism and Synthetic Applications: Chemistry reactive intermediates, carbine, nitrene, benzyne, Hofmann-Curtius-Lossen rearrangement, Wolf rearrangement, Simmons-Smith reaction, Reimer- Tiemann reaction, Michael reaction, Darzens reaction, Witting reaction, McMurry reaction. Pinacol-pinacolone, Favorskii, benzilic acid rearrangement, dienonc-phenol rearrangement, Bayer-Villeger reaction). Oxidation and reduction reactions in organic chemistry. Organometallic reagents in organic synthesis (Grignard and organocopper). Diels-Alder reaction, Sigmatropic reactions. Qualitative Organic Analysis: Functional group interconversions, structural problems using chemical reactions, identification of functional groups by chemical tests, elementary 1H NMR and IR spectroscopy as a tool for structural elucidation. Natural Products Chemistry : Introductory chemistry of alkaloids, terpenes, carbohydrates, amino acids, peptides and nucleic acids. Heterocyclic Chemistry: Monocyclic compounds with one hetero atom. INORGANIC CHEMISTRY Periodic Table: Periodic classification of elements and periodicity in properties; general methods of isolation and purification of elements. Chemical Bonding and Shapes of Compounds: Types of bonding; VSEPR theory and shapes of molecules; hybridization; dipole moment; ionic solids; structure of NaCl, CsCl, diamond and graphite; lattice energy. Main Group Elements (s and p blocks): Chemistry with emphasis on group relationship and gradation in properties; structure of electron deficient compounds of main groupelements and application of main group elements. Transition Metals (d block): Characteristics of 3d elements; oxide, hydroxide and salts of first row metals; coordination complexes; VB and Crystal Field theoretical approaches for structure, colour and magnetic properties of metal complexes. Organometallic compounds, metal carnonyls, nitrosyls and metallocenes, ligands with back bonding capabilities; MO theory approaches to explain bonding in metal-carbonyl, metal-nitrosyl and metalphosphine complexes. Bioinorganic Chemistry: Essentials and trace elements of life, basic reactions in the biological systems and the role of metal ions especially Fe2+, Fe3+, Cu2+ and Zn2+, function of hemoglobin and myoglobin. Instrumental Methods of Analysis: Basic principles, instrumentations and simple applications of conductometry, potentiometry, UV-vis spectro-photometry, analysis of water, air and soil samples. Analytical Chemistry: Principles of qualitative and quantitative analysis; acid-base, oxidation-reduction and EDTA and precipitation reactions; use of indicators; use of organic reagents in inorganic analysis; radioactivity; nuclear reactions; applications of isotopes. If you want to prepare for this exam then I will suggest you that R.K. Gupta is best book for this you can purchase it by book store and online also. |
26th September 2012 04:46 PM | |
madmankart.3 | IIT Jam Chemistry Books I have applied for the exam of the IIT JAM now I am looking for the syllabus and also I want to know about the best reference book for this. |