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Re: University Of Kerala PG Syllabus
As you want here I am providing University of Kerala Post graduate (PG) programmes in chemistry syllabus on your demand : SEMESTER I CH 211 INORGANIC CHEMISTRY - I Total 90 h Unit I Noble gases, halogens, isopoly and heteropoly acids 18 h Noble gas compounds: Preparation, properties, structure and bonding. Halogens in positive oxidation states. Preparation, properties, structure, bonding and uses of inter halogen compounds, pseudo halogens, poly halide ions. Astatine: Synthesis, stability and properties. Preparation, properties and structure of isopoly and heteropoly acids of Mo and W. Classification, preparation, properties and structure of borides, carbides, nitrides and silicides. Classification and structure of silicates. Properties and structure of aluminosilicates and zeolites. Preparation, properties and applications of silicones. Unit II Coordination chemistry-I: Theories of metal complexes 18 h Types of ligands and complexes. Isomerism: Geometrical, optical and structural isomerism. Stability of complex ions in aqueous solutions: Formation constants. Stepwise and overall formation constants. Factors affecting stability of complexes. Trends in stepwise constants. Determination of stability constants: spectrophotometric, polarographic and potentiometric methods. Stability of chelates. Thermodynamic explanation, macrocyclic effects. Crystal field theory: Splitting of d orbitals in octahedral, tetragonal, square planar, tetrahedral, trigonal bipyramidal and square pyramidal fields. Jahn-Teller theorem, dynamic- static -evidence for JT effect. Crystal field stabilization energy (CFSE) and its calculations. Octahedral Site Stabilization Energy. Thermodynamic effects of CFSE. Factors affecting the splitting parameter. Spectrochemical series. Ligand field theory. Molecular orbital theory. Sigma and pi bondings in complexes. MO diagrams of octahedral complexes with and without pi bonds. Effect of pi bond on the stability of sigma bond. Nephelauxetic effect. Critical comparison of the three theories University of Kerala Post graduate (PG) programmes in chemistry syllabus |
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