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Old 9th March 2020, 05:35 PM
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Default University Of Kerala PG Syllabus

I am looking for University of Kerala Post graduate (PG) programmes in chemistry syllabus , so would you plz provide me same here , if you have it this time ??
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Old 9th March 2020, 10:03 PM
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Default Re: University Of Kerala PG Syllabus

As you want here I am providing University of Kerala Post graduate (PG) programmes in chemistry syllabus on your demand :

SEMESTER I
CH 211 INORGANIC CHEMISTRY - I
Total 90 h
Unit I Noble gases, halogens, isopoly and heteropoly acids
18 h
Noble gas compounds: Preparation, properties, structure and bonding. Halogens in
positive oxidation states. Preparation, properties, structure, bonding and uses of inter halogen
compounds, pseudo halogens, poly halide ions. Astatine: Synthesis, stability and properties.
Preparation, properties and structure of isopoly and heteropoly acids of Mo and W.
Classification, preparation, properties and structure of borides, carbides, nitrides and
silicides. Classification and structure of silicates. Properties and structure of aluminosilicates
and zeolites. Preparation, properties and applications of silicones.
Unit II Coordination chemistry-I: Theories of metal complexes
18 h
Types of ligands and complexes. Isomerism: Geometrical, optical and structural
isomerism. Stability of complex ions in aqueous solutions: Formation constants. Stepwise
and overall formation constants. Factors affecting stability of complexes. Trends in stepwise
constants. Determination of stability constants: spectrophotometric, polarographic and
potentiometric methods. Stability of chelates. Thermodynamic explanation, macrocyclic
effects.
Crystal field theory: Splitting of d orbitals in octahedral, tetragonal, square planar,
tetrahedral, trigonal bipyramidal and square pyramidal fields. Jahn-Teller theorem, dynamic-
static -evidence for JT effect. Crystal field stabilization energy (CFSE) and its calculations.
Octahedral Site Stabilization Energy. Thermodynamic effects of CFSE. Factors affecting the
splitting parameter. Spectrochemical series. Ligand field theory. Molecular orbital theory.
Sigma and pi bondings in complexes. MO diagrams of octahedral complexes with and
without pi bonds. Effect of pi bond on the stability of sigma bond. Nephelauxetic effect.
Critical comparison of the three theories

University of Kerala Post graduate (PG) programmes in chemistry syllabus




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