MP Higher Education Syllabus B.Sc Chemistry

Hii sir, I Wants to get the Syllabus of the - Physical Chemistry Subject of the BSc Chemistry Course of the Department of Higher Education, Govt. of M.P. ?

[shikha]

As you Asking for the Syllabus of the - Physical Chemistry Subject of the BSc Chemistry Course of the Department of Higher Education, Govt. of M.P. the Syllabus is given below


I- Physical Chemistry

Unit - 1liquid-liquid mixtures
Ideal liquid mixtures, Raoult's and Henry s law. Non-ideal system azeotropes :
HCl-H20 and ethanol - water systems.

Partially miscible liquids - Phenol-water, trimethylamine-water, nicotine-water
systems. Lower and upper consolute temperature. Effect of impurity on consolute
temperature. Immiscible liquids, steam distillation. Nernst distribution law - thermodynamic derivation, applications.

Unit 2 Electrochemistry -1 6 Hrs
Electrical transport - Conduction in metals and in electrolyte solutions, specific
conductance and equivalent conductance, measurement of equivalent
conductance, variation of equivalent and specific conductance with dilution.
Migration of ions and Kohlrausch law.

Debye-Huckel-Onsager s equation for strong electrolytes (elementary treatment
only). Transport number, definition and determination by Hittorf method and
moving boundary method. Applications of conductivity measurements :
determination of degree of dissociation, determination of Ka of acids,
determination of solubility product of a sparingly soluble salt, conductometric
titrations.

Unit 3 Electrochemistry II
Types of reversible electrodes : gas metal ion, metal-metal ion, metal-insoluble
salt-anion and redox electrodes. Electrode reactions. Nernst equation, derivation
of cell E.M.F. and single electrode potential, standard hydrogen electrodereference
electrodes-standard electrode potential, sign conventions,electrochemical series and its significance. Electrolytic and Galvanic cells, reversible and irreversible cells, conventional representation of electrochemical
cells.

Unit 4 Electrochemistry and Corrosion 6 Hrs.
Concentration cells with and without transport, liquid junction potential,
application of conc cells, valency of ions, solubility product and activity
coefficient, potentiometric titrations.
Definition of pH and pK, determination of PH using hydrogen, quinhydrone

Syllabus of the - Physical Chemistry Subject of the BSc Chemistry Course of the Department of Higher Education, Govt. of M.P